Exploring the Use of Silver Cathodes which Possess Exceptional Catalytic Activity
As part of our research in electrochemistry, we are exploring the use of silver cathodes which possess exceptional catalytic activity toward the reduction of halogenated organic compounds. Direct reduction of 6-iodo-1-phenyl-1-hexyne at a silver cathode in dimethylformamide affords benzylidenecyclopentane in nearly quantitative yield (an impossibility if a carbon or mercury electrode is employed).
In other work, a protocol based on stripping analysis has been devised to determine trihalomethanes (THMs) at concentrations of 10–100 nM in drinking water. This range brackets the limits of THM contamination mandated by the Environmental Protection Agency (EPA).
Distinguished Professor
Robert & Marjorie Mann Chair
Distinguished Professor
Linda & Jack Gill Chair in Biomolecular Science
James F. Jackson Professor of Chemistry
Class of 1948 Herman B Wells Endowed Professor
Adjunct Professor, Physics
Associate Dean of Natural and Mathematical Sciences and Research
Associate Professor (O'Neill School of Public and Environmental Affairs),
Adjunct Professor (Chemistry)
Rudy Professor (O'Neill School of Public and Environmental Affairs)
Adjunct Professor (Chemistry)
Professor & Associate Vice President for Engagement
Professor, Department of Molecular and Cellular Biochemistry
Adjunct Professor